单块集尘板振打加速度的有限元分析

采用有限元分析软件ABAQUS，对单块集尘板振打加速度进行了分析计算。并将计算结果与解析法和实测法结果进行对比。对比结果表明，有限元计算值更接近于实测值。用有限元法对某厂实际运行的电除尘器加速度进行求解，计算结果与实际基本吻合。由于有限元法能非常方便地处理各种复杂板型、不同的悬挂方式、振打锤的大小以及振打方式，因此，有限元法对于现有极板的分析与新型极板的研究均具有重要的实际意义。     

基于可拓学石化装置失效后果严重度评估方法研究

石化企业中，石化装置的安全运行对保证企业的安全生产起到关键作用，其一旦失效发生事故，将导致巨大的人员伤亡及财产损失。因此，开展石化装置失效后果严重性的评价研究，对保证石化企业的安全生产具有重要意义。本文根据物元可拓性理论，结合石化装置失效后果的严重性情况，运用可拓评判方法建立石化装置失效后果严重度的综合评判模型，给出了评价步骤，最终确定设备失效后果的严重程度。研究结果表明，该方法可应用于多层次的工程风险评价问题，从而为石化工程项目风险管理提供了一种有效的分析方法。     

Ionic dye adsorption by zinc oxide nanoparticles

The adsorption behaviour of Basic Red 12, Acid Orange 7 and Acid Blue 1 on zinc oxide nanoparticles (ZNP) has been investigated to understand the physicochemical process involved and to explore the possible use of nanoparticles in the treatment and management of textile waste matter. The dye removal capacity of ZNP towards Basic Red 12, Acid Orange 7 and Acid Blue 1 was found to be 15.64, 6.78 and 6.38 mg g^?1, respectively. The adsorption process was pH dependent and optimum pH values of 9.0, 2.0 and 4.0 were obtained for Basic Red 12, Acid Orange 7 and Acid Blue 1, respectively. Equilibrium was established after 1.0 h for all dyes. Langmuir, Freundlich and Temkin isotherm models were applied to the system. The adsorbent ZNP was characterised using scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET) and Fourier transform infrared (FTIR) techniques. SEM analysis revealed the noticeable nanoporous morphology of the material. The results of FTIR spectroscopy showed that the process is driven by an electrostatic complexation mechanism. XRD studies revealed the nanocrystalline structure of ZNP. BET surface area measurement suggested a high pore volume and large surface area for the adsorbent. The kinetic measurements suggested pseudo-second-order kinetic processes with high regression coefficients and smaller standard error of estimate values and lower residual sum of squares. The thermodynamic measurements suggested that all processes were exothermic and accompanied by negative values for Δ G⁰, Δ S⁰ and Δ H⁰.     

原子吸收法直接测量土壤中的汞含量

实验采用DMA-80自动测汞仪直接测定土壤中的汞含量，详细介绍了土壤样品中汞分析条件的选择，方法在0．4—400ng范围内，线性良好，其检出限为0．2ug／kg。     

以羟胺为底物的自养脱氮微量热研究

羟胺（NH₂OH）是单级自养脱氮系统物质转化的重要中间产物。从稳定运行（氨氮去除率维持90%以上，总氮去除率维持在80%以上）的单级自养脱氮工艺（SBBR）取活性污泥放入量热池，加入不同浓度N-NH₂OH（40～200 mg/L）进行量热实验研究。结果表明，用Boltzmann模型可以很好地表达量热值与NH₂OH浓度的关系，超过一定浓度的羟胺会抑制微生物活性，自营养脱氮过程的产热增量降低。     

A hybrid method for quasi-three-dimensional slope stability analysis in a municipal solid waste landfill

Limited space for accommodating the ever increasing mounds of municipal solid waste (MSW) demands the capacity of MSW landfill be maximized by building landfills to greater heights with steeper slopes. This situation has raised concerns regarding the stability of high MSW landfills. A hybrid method for quasi-three-dimensional slope stability analysis based on the finite element stress analysis was applied in a case study at a MSW landfill in north-east Spain. Potential slides can be assumed to be located within the waste mass due to the lack of weak foundation soils and geosynthetic membranes at the landfill base. The only triggering factor of deep-seated slope failure is the higher leachate level and the relatively high and steep slope in the front. The valley-shaped geometry and layered construction procedure at the site make three-dimensional slope stability analyses necessary for this landfill. In the finite element stress analysis, variations of leachate level during construction and continuous settlement of the landfill were taken into account. The "equivalent" three-dimensional factor of safety (FoS) was computed from the individual result of the two-dimensional analysis for a series of evenly spaced cross sections within the potential sliding body. Results indicate that the hybrid method for quasi-three-dimensional slope stability analysis adopted in this paper is capable of locating roughly the spatial position of the potential sliding mass. This easy to manipulate method can serve as an engineering tool in the preliminary estimate of the FoS as well as the approximate position and extent of the potential sliding mass. The result that FoS obtained from three-dimensional analysis increases as much as 50% compared to that from two-dimensional analysis implies the significance of the three-dimensional effect for this study-case. Influences of shear parameters, time elapse after landfill closure, leachate level as well as unit weight of waste on FoS were also investigated in this paper. These sensitivity analyses serve as the guidelines of construction practices and operating procedures for the MSW landfill under study.     

衡山PM_（2.5）中痕量金属元素的分析

建立了微波消解-电感耦合等离子体质谱法同时测定PM2.5中12种痕量金属元素的方法。对不同消解体系进行了讨论,确定采用HNO3＋H2O2消解体系。方法检出限在0.01～6.4 ng/m3之间,精密度为0.5%～8.9%,加标回收率在69.2%～92.6%之间。应用该方法测定了衡山PM2.5中痕量金属元素的含量,讨论了痕量元素的浓度分布特征,对各元素进行了相关性分析,并应用富集因子法对来源进行了分析。     

LEAD AND CADMIUM ASSOCIATED WITH SALTWATER INTRUSION IN A NEW JERSEY AQUIFER SYSTEM1

ABSTRACT: The U.S. Geological Survey collected ground-water samples from the upper and middle aquifers of the Potomac-Raritan-Magothy aquifer system in a 400-square-mile area of New Jersey from 1984 through 1986. Concentrations of lead were greater than the U.S. Environmental Protection Agency maximum contaminant level (MCL) of 50 micrograms per liter in water from 16 of 239 wells. The cencentrations of cadmium were greater than the MCL of 10 micrograms per liter in water from 10 to 241 wells. One-half of the wells that exceeded the lead MCL were in known areas of saltwater intrusion, as were all 10 wells that exceeded the cadmium MCL. The association of elevated concentrations of these metals with elevated concentrations of chloride indicates a mochanism related to saltwater intrusion.     

MODEL FOR PREDICTING TRANSPORT OF PESTICIDES AND THEIR METABOLITES IN THE UNSATURATED ZONE1

ABSTRACT: A finite element model based on Galerkin's upstream weighted residual technique was developed to predict the simultaneous convective-dispersion transport and transformations of pesticides and their metabolites in the unsaturated zone. Transformations of the parent compound and its metabolites were assumed to be first-order reactions for oxidation and hydrolysis, while adsorption of the pesticide species (parent compound and metabolites) to the soil components was assumed to be represented by a linear equilibrium (Freundlich type) isotherm. Volatilization and plant root uptake of pesticides in the solution phase were neglected in the analysis. The proposed model was used to simulate the transport and transformation of aldicarb and its metabolites, aldicarb sulfoxide and aldicarb sulfone, in the soil profile. Several examples are used to demonstrate the accuracy, validity, and applicability of the proposed model. Simulated results indicate that the proposed model can potentially be used to estimate the mass flux of water, and pesticide and pesticide metabolite concentrations in the subsurface environment. However, further verification of the model against actual field data is needed to fully demonstrate the model's potential.     

DISTRIBUTION AND GRAIN-SIZE PARTITIONING OF METALS IN BOVFOM SEDIMENTS OF AN EXPERIMENTALLY ACIDIFIED WISCONSIN LAKE1

ABSTRACT: A study of concentrations and distribution of major and trace elements in surficial bottom sediments of Little Rock Lake in northern Wisconsin included examination of spatial variation and grain-size effects. No significant differences with respect to metal distribution in sediments were observed between the two basins of the lake, despite the experimental acidification of one of the basins from pH 6.1 to 4.6. The concentrations of most elements in the lake sediments were generally similar to soil concentrations in the area and were well below sediment quality criteria. Two exceptions were lead and zinc, whose concentrations in July 1990 exceeded the criteria of 50 μg/g and 100 μg/g, respectively, in both littoral and pelagic sediments. Concentrations of some elements, particularly Cu, Pb, and Zn, increased along transects from nearshore to midlake, following a similar gradient of sedimentary organic carbon. In contrast, Mn, Fe, and alkali/alkaline-earth elements were at maximum concentrations in nearshore sediments. These elements are less likely to partition to organic particles, and their distribution is more dependent on mineralogical composition, grain size, and other factors. Element concentrations varied among different sediment grain-size fractions, although a simple inverse relation to grain size was not observed. Fe, Mn, Pb, and Zn were more concentrated in a grain-size range 20–60 tm than in either the very fine or the coarse fractions, possibly because of the aggregation of smaller particles cemented together by organic and Fe/Mn hydrous-oxide coatings.